HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl Alcohol → 1-(2-Bromophenyl)ethanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl Alcohol | HCID 244 | — |
| Reactant | 2-Bromobenzyl alcohol | HCID 72850 | — |
| Reactant | Tricyclohexyl [o-(1-hydroxyethyl)phenyl]tin | HCID 19359512 | — |
| Product | 1-(2-Bromophenyl)ethanol | HCID 95455 | 75.1% |
Reaction Steps
17.2 g of o-[tri(cyclohexyl)]tin]benzylalcohol was obtained in the same manner as in the synthesis of tricyclohexyl[o-(1-hydroxyethyl)phenyl]tin of Example 1-(4), with the exception that 9.40 g of o-bromobenzylalcohol (50.2 mmol), prepared in the aforementioned example (1), instead of o-bromo-1-phenyl ethanol (yield=75.1%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06022822 |
| Source dataset | uspto-grants-2000_02 |
| ORD ID | ord-3367da7ec83a4b569278ddffb8d8c220 |
| Source note | uspto-grants-2000_02 |