HRID376942

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID24387

Phosphorous trichloride

Cl3P

HCID2755260

1-(1-Naphthyl)-2-naphthol

C20H14O

结构：C=Cc1ccc2c(-c3c(P(c4ccccc4)c4ccccc4)ccc4ccccc34)c(O)ccc2c1

HCID17765396

未命名化合物

PRODUCTS

生成物

结构：C=Cc1ccc2c(-c3c(P(c4ccccc4)c4ccccc4)ccc4ccccc34)c(Oc3ccc4ccccc4c3-c3c(OP)ccc4ccccc34)ccc2c1

HCID86755122

未命名化合物

PROCEDURE

实验过程

Finally, 1,1'-binaphthalene-2,2'-dioxychlorophosphine (XIV), obtained, e.g., by heating an optically active binaphthol (VII) together with phosphorus trichloride, is reacted with the 2'-diphenylphosphino-2-hydroxy-6-vinyl-1,1'-binaphthyl (XIII) obtained above, whereby 2'-diphenylphosphino-6-vinyl-1,1'-binaphthalen-2-yloxy(1,1'-binaphthalene-2,2'-diyloxy)phosphine (XV) is obtained as the target compound.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-810a00dc80a34242a66a6969d626a9fd
来源数据集: uspto-grants-2000_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06022936
来源说明: uspto-grants-2000_02

反应 SMILES

[C:1]1([C:12]2[C:21]3[C:16](=[CH:17][CH:18]=[CH:19][CH:20]=3)[CH:15]=[CH:14][CH:13]=2)[C:2]([OH:11])=[CH:3][CH:4]=[C:5]2[C:10]=1[CH:9]=[CH:8][CH:7]=[CH:6]2.[P:22](Cl)(Cl)Cl.[C:26]1([P:32]([C:56]2[CH:61]=[CH:60][CH:59]=[CH:58][CH:57]=2)[C:33]2[CH:42]=[CH:41][C:40]3[C:35](=[CH:36][CH:37]=[CH:38][CH:39]=3)[C:34]=2[C:43]2[C:52]3[C:47](=[CH:48][C:49]([CH:53]=[CH2:54])=[CH:50][CH:51]=3)[CH:46]=[CH:45][C:44]=2[OH:55])[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1>>[C:56]1([P:32]([C:26]2[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=2)[C:33]2[CH:42]=[CH:41][C:40]3[C:35](=[CH:36][CH:37]=[CH:38][CH:39]=3)[C:34]=2[C:43]2[C:52]3[C:47](=[CH:48][C:49]([CH:53]=[CH2:54])=[CH:50][CH:51]=3)[CH:46]=[CH:45][C:44]=2[O:55][C:13]2[CH:14]=[CH:15][C:16]3[C:21](=[CH:20][CH:19]=[CH:18][CH:17]=3)[C:12]=2[C:1]2[C:10]3[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=3)[CH:4]=[CH:3][C:2]=2[O:11][PH2:22])[CH:57]=[CH:58][CH:59]=[CH:60][CH:61]=1