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HRID37742

反应详情

EQUATION

反应方程式

HRID 37742 的结构方程式

REACTANTS

反应物

2
结构：O=S(=O)(Cl)c1ccc(Oc2ccc(Br)cc2)cc1
HCID12249741

4-(4-bromophenoxy)benzenesulfonyl chloride

C12H8BrClO3S

结构：CC(C)(C)OC(=O)CN(CC(=O)OC(C)(C)C)S(=O)(=O)c1ccc(Oc2ccccc2)cc1
HCID66916713

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)OC(=O)CN(CC(=O)OC(C)(C)C)S(=O)(=O)c1ccc(Oc2ccc(Br)cc2)cc1
HCID67312686

未命名化合物

PROCEDURE

实验过程

Compound 4d was prepared similar to the procedure described for 4a using 4-(4-bromophenoxy)-benzenesulphonyl chloride (3d) (3.00 g, 8.63 mmol). Yield: 4.13 g, 7.42 mmol, 86% (light yellow solid). 1H NMR (DMSO-d6): δ 7.70 (d, J=8.2 Hz, 2H, ArH), 7.52 (d, J=8.8 Hz, 2H, ArH), 7.01 (d, 3J=8.8 Hz, 2H, ArH), 6.67 (d, 3J=8.9 Hz, 2H, ArH) 4.05 (s, 4H, 2×CH2CO2 tBu), 1.46 (s, 18H, 2×CO2tBu).