Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4-Butylbenzaldehyde → HCID 54004981, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4-Butylbenzaldehyde | HCID 70988 | — |
| 반응물 | (5-Carboxypentyl)triphenylphosphanium bromide | HCID 2779280 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | HCID 54004981 | HCID 54004981 | 51.3% |
반응 단계
This compound was synthesized from 5-carboxypentyltriphenylphosphonium bromide (9.50 g, 20 mmol) and p-butylbenzaldehyde (3.24 g, 20 mmol) in THF (100 mL) by a Wittig reaction. Kugelrohr distillation yielded the product (2.67 g, 51%) as a colorless oil (bp 154-157° C./0.05 torr). IR: 3400-2500, 1720 cm-1, 1H-NMR:0.92 (t, 3H), 1.50 (m, 8H), 2.30 (m, 4H), 2.58 (m, 2H), 5.58+6.15 (m, 1H), 6.38 (t, 1H), 7.18 (m, 4H), 10.30 (bs, 1H). Anal. Calcd. for C17H24O2 : C, 78.42, H, 9.29%; Found: C, 78.38, H. 9.29%. Z:E=62:38.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06025511 |
| 출처 데이터셋 | uspto-grants-2000_02 |
| ORD ID | ord-9e6356d10b49428392f2be608e0c0a3e |
| 출처 메모 | uspto-grants-2000_02 |