HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylamine → HCID 54412888, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylamine | HCID 674 | — |
| Reactant | Formaldehyde | HCID 712 | — |
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | 2,4-Di-tert-butylphenol | HCID 7311 | — |
| Reactant | Methyl Thioglycolate | HCID 16907 | — |
| Product | HCID 54412888 | HCID 54412888 | — |
Reaction Steps
50.96 g (0.247 mol) of 2,4-di-t-butylphenol, 28.84 g (0.272 mol) of methyl thioglycolate, 14.83 g (0.494 mol) of paraformaldehyde and 3.41 g of dimethylamine (33% in ethanol) are refluxed for 18 hours in 50 ml of DMF. The crude product (85.3 g) can, after working-up as described above, be further purified by flash chromatography. m.p. 55.0-55.5° C. Analysis for C18H28SO3 : calc. C, 66.63; H, 8.70; S 9.88%; found C 66.65; H 8.79; S 9.88%
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06028131 |
| Source dataset | uspto-grants-2000_02 |
| ORD ID | ord-984f85017d274bbbae996576d2f7e856 |
| Source note | uspto-grants-2000_02 |