Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Toluene | HCID 1140 | — |
| Reactant | 2,3-Dihydroxybutanedioate | HCID 3806114 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | HCID 19353129 | HCID 19353129 | — |
| Reactant | Diisobutylaluminumhydride | HCID 21225700 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 19353138 | HCID 19353138 | — |
Reaction Steps
A 1M diisobutylaluminium hydride solution in toluene (2.78 ml, 2.78 mmol) is added at 78° C., dropwise, to a solution of methyl 2-(5,5,8,8-Tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)acrylate (310 mg, 1.14 mmol) in dichloromethane (3 ml). The solution is stirred for 1 h at 0° C., then treated with a solution of double tartrate of sodium [lacuna] and filtered through silica.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06030952 |
|---|
| Source dataset | uspto-grants-2000_02 |
|---|
| ORD ID | ord-cd3a3b29d94f4fe5a3f3c5cd6839d6fd |
|---|
| Source note | uspto-grants-2000_02 |
|---|
