HCID 19354286, compound → HCID 19354277, compound

HRID 378577Notes

Reaction equation

HRID 378577 reaction equation
C(OC(=O)C(C1([N+]([O-])=O)CCCC1C)C(OCC)=O)C.[N+:21]([CH2:24][C:25]1([CH:31]([C:37]([O:39][CH2:40][CH3:41])=[O:38])[C:32]([O:34][CH2:35][CH3:36])=[O:33])[CH2:30][CH2:29][CH2:28]CC1)([O-:23])=[O:22]>>[CH2:40]([O:39][C:37](=[O:38])[CH:31]([C:25]1([CH2:24][N+:21]([O-:23])=[O:22])[CH2:30][CH2:29][CH2:28]1)[C:32]([O:34][CH2:35][CH3:36])=[O:33])[CH3:41]

Participants

3

Reactant 2

HCID 19354286HCID 19354286, compound2×HCID 57201157HCID 57201157, compound2×

Product 1

HCID 19354277HCID 19354277, compound

Procedure

Using a similar procedure, diethyl(1-nitro-methyl-1-cyclopentyl)malonate (compound 64) (1H-NMR (CDCl3) δ ppm: 1.27 (6H, t, J=7 Hz), 1.6-2.0 (8H, m), 3.79 (1H, s), 4.20 (4H, q, J=7 Hz), 4.71 (2H, s)) and diethyl (1-nitromethyl-1-cyclohexyl)malonate (compound 65) (1H-NMR (CDCl3) δ ppm: 1.27 (6H, t, J=7 Hz), 1.4-1.8 (10H, m), 3.88 (1H, s), 4.20 (4H, q, J=7 Hz), 4.96 (2H, s) were obtained.

Workup

  1. customwere obtained

Sources & evidence

ORD record
ord-c01461328c1847808a65eab33320454a
Source dataset
uspto-grants-2000_02
Patent number
US06031102

Reaction notes

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