HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nitrogen → Di-tert-butyl ether
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nitrogen | HCID 947 | — |
| Reactant | tert-Butanol | HCID 6386 | — |
| Reactant | 1-Hexanol | HCID 8103 | — |
| Reactant | Hexyl t-butyl ether | HCID 547839 | — |
| Product | Di-tert-butyl ether | HCID 22541 | — |
Reaction Steps
300 mmoles of t-butanol, 100 mmoles of 1-hexanol and 2.5 g of Ti-Si-catalyst powder are stirred in a 100 ml autoclave at a pressure of 40 bar N2 and a temperature of 150° C. over a period of 17 h, 17% of n hexanol were converted into hexyl t-butyl ether with a selectivity of 90%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06297180B1 |
| Source dataset | uspto-grants-2001_10 |
| ORD ID | ord-c4b88dc8fc2f43d4a6be06585468b591 |
| Source note | uspto-grants-2001_10 |