HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetone → HCID 21696738, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetone | HCID 180 | — |
| Reactant | Sodium Azide | HCID 33557 | — |
| Reactant | Azide | HCID 33558 | — |
| Reactant | 2-Acetoxybenzoyl chloride | HCID 79668 | — |
| Solvent | Benzene | HCID 241 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 21696738 | HCID 21696738 | — |
| Product | HCID 53807589 | HCID 53807589 | — |
Reaction Steps
2-Acetylbenzoic acid azide was prepared by reacting 2-acetoxybenzoyl chloride with sodium azide in acetone and water at 0-5° C. for 24 hours. It had an IR peak at 2245 cm−1 (azide). The crude azide was then heated in benzene at 70-75° C. under nitrogen for 2 hours to give 2-acetoxyphenylisocyanate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06297230B1 |
| Source dataset | uspto-grants-2001_10 |
| ORD ID | ord-54277eff264547459f34b3f551fb52be |
| Source note | uspto-grants-2001_10 |