HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → Methylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Nitromethane | HCID 6375 | — |
| Reactant | 4-(5-Phenylpentyloxy)-3-methoxy-benzaldehyde | HCID 21697287 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Methylamine | HCID 6329 | — |
| Product | 1-(5-Phenylpentyloxy)-2-methoxy-4-(2-nitro-vinyl)-benzene | HCID 54150508 | — |
Reaction Steps
Operating analogously to example 2 using 4-(5-phenylpentyloxy)-3-methoxy-benzaldehyde (21 g, 73.4 mmoles), obtained as described in example 21, in methanol (86 ml), 8.03M methylamine in ethanol (1.92 ml, 15.4 mmoles), acetic acid (0.88 ml, 15.4 mmoles) and nitromethane (4.34 ml, 80.7 mmoles) 20 g of the title product were obtained (yield: 80%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06297257B1 |
| Source dataset | uspto-grants-2001_10 |
| ORD ID | ord-f98f33e9f9bd44ef92de8a8a996bd8e0 |
| Source note | uspto-grants-2001_10 |