Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Phosphorus oxychloride | HCID 24813 | — |
| Reactant | 1-Undecanol, 2-heptyl- | HCID 95338 | — |
| Solvent | Hexane | HCID 8058 | — |
Reaction Steps
To 14.6 g (0.095 mol) of phosphorus oxychloride in hexane, 51.4 g (0.190 mol) of 2-heptylundecyl alcohol, 19.2 g (0.190 mol) of triethylamine in hexane were added dropwise while maintaining the temperature at not higher than 0° C. After ripening the mixture at 25° C., a hydrochloric acid salt of triethylamine was removed by washing. The solvent was also removed to obtain 59.1 g (0.095 mol) of bis(2-heptylundecyl) phosphoric chloride (not less than 95% purity was confirmed by 31-NMR)
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06299887B1 |
|---|
| Source dataset | uspto-grants-2001_10 |
|---|
| ORD ID | ord-67fcadb3c3e24c77ab7bffdd41eb60ce |
|---|
| Source note | uspto-grants-2001_10 |
|---|
