HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nitrobenzene → Dimethyl phenanthrene-3,4-dicarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nitrobenzene | HCID 7416 | — |
| Reactant | 2-Vinylnaphthalene | HCID 13230 | — |
| Reactant | HCID 86613298 | HCID 86613298 | — |
| Product | Dimethyl phenanthrene-3,4-dicarboxylate | HCID 15075419 | — |
Reaction Steps
A solution of 65 mmol of 2-vinylnaphthalene and 68 mmol of methyl acetylene-dicarboxylate in 200 ml of nitrobenzene is maintained at reflux for 14 hours. After distillation of the solvent, the reaction medium is chromatographed on silica (eluent: CH2Cl2) in order to obtain the expected product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06300340B1 |
| Source dataset | uspto-grants-2001_10 |
| ORD ID | ord-f13ee31e844043908b56df1cb1976e0b |
| Source note | uspto-grants-2001_10 |