Thionyl Chloride → HCID 18364483, compound

HRID 380280Notes

Reaction equation

HRID 380280 reaction equation
S(Cl)([Cl:3])=O.[CH3:5][C:6]1[CH:11]=[C:10]([CH3:12])[CH:9]=[C:8]([CH3:13])[C:7]=1[Bi:14]([C:24]1[C:29]([CH3:30])=[CH:28][C:27]([CH3:31])=[CH:26][C:25]=1[CH3:32])[C:15]1[C:20]([CH3:21])=[CH:19][C:18]([CH3:22])=[CH:17][C:16]=1[CH3:23]>CCCCCC>[Cl-:3].[Cl-:3].[CH3:23][C:16]1[CH:17]=[C:18]([CH3:22])[CH:19]=[C:20]([CH3:21])[C:15]=1[Bi:14]([C:24]1[C:25]([CH3:32])=[CH:26][C:27]([CH3:31])=[CH:28][C:29]=1[CH3:30])[C:7]1[C:6]([CH3:5])=[CH:11][C:10]([CH3:12])=[CH:9][C:8]=1[CH3:13]

Participants

4

Reactant 2

HCID 24386Thionyl ChlorideHCID 4670734HCID 4670734, compound

Product 1

HCID 18364483HCID 18364483, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

Thionyl chloride (1.48 g, 11 mmol) was added to a solution of tris(2,4,6-trimethylphenyl)bismuthine (Example 14) (5.66 g, 10 mmol) in hexane (100 ml) at ambient temperature. The mixture was stirred for one hour and the precipitated product was isolated and recrystalized from ethanol. Yield: 5.70 g (90%).

Workup

  1. customthe precipitated product was isolated
  2. customrecrystalized from ethanol

Sources & evidence

ORD record
ord-e3e1745b92684cbd94fbf4be655a8238
Source dataset
uspto-grants-2001_10
Patent number
US06303101B1

Reaction notes

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