Potassium peroxymonosulphate → HCID 18362945, compound

HRID 381304Notes

Reaction equation

HRID 381304 reaction equation
[CH3:1][N:2]1[C:7](=[O:8])[C:6]2=[C:9]([S:23][C:24]3[CH:29]=[CH:28][CH:27]=[CH:26][N:25]=3)[N:10]([CH2:12][C:13]3[C:22]4[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=4)[CH:16]=[CH:15][CH:14]=3)[CH:11]=[C:5]2[N:4]([CH2:30][CH:31]([CH3:33])[CH3:32])[C:3]1=[O:34].S([O-])(O[O-])(=O)=[O:36].[K+].[K+].OOS([O-])=O.[K+]>>[CH3:1][N:2]1[C:7](=[O:8])[C:6]2=[C:9]([S:23]([C:24]3[CH:29]=[CH:28][CH:27]=[CH:26][N:25]=3)=[O:36])[N:10]([CH2:12][C:13]3[C:22]4[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=4)[CH:16]=[CH:15][CH:14]=3)[CH:11]=[C:5]2[N:4]([CH2:30][CH:31]([CH3:32])[CH3:33])[C:3]1=[O:34]

Participants

4

Reactant 3

HCID 10313463Potassium peroxymonosulphateHCID 18362941HCID 18362941, compoundHCID 23707502Potassium hydroxy sulfite

Product 1

HCID 18362945HCID 18362945, compound

Procedure

Prepared from the compound of Example 20, 3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)-5-[(2-pyridinyl)thio]-1H-pyrrolo[3,4-d]pyrimidine-2,4(3H,6H)-dione and potassium peroxymonosulphate (commercially sold under the trade mark “OXONE”) following the method of Example 8 c).

Sources & evidence

ORD record
ord-3805e9f726674922b321232b5c4451a2
Source dataset
uspto-grants-2001_10
Patent number
US06306863B1

Reaction notes

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