Chlorotrimethylsilane → HCID 54503112, compound

HRID 382388Notes

Reaction equation

HRID 382388 reaction equation
[CH2:1]([O:8][C:9]1[CH:24]=[CH:23][C:12]([C:13](O)([C:18]([CH3:21])([CH3:20])[CH3:19])[C:14]([CH3:17])([CH3:16])[CH3:15])=[CH:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Cl:25][Si](C)(C)C>CS(C)=O>[CH2:1]([O:8][C:9]1[CH:24]=[CH:23][C:12]([C:13]([Cl:25])([C:18]([CH3:21])([CH3:20])[CH3:19])[C:14]([CH3:17])([CH3:16])[CH3:15])=[CH:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 6397ChlorotrimethylsilaneHCID 53643340HCID 53643340, compound

Product 1

HCID 54503112HCID 54503112, compound

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

A reaction and post-treatment were conducted following the conditions of Example 71 using 5.40 g (13.65 mmol) of 4-benzyloxy-di-t-butylbenzyl alcohol, 80 ml of chlorotrimethylsilane, and 1.07 ml of dimethylsulfoxide, to obtain 4-benzyloxy-di-t-butylbenzyl chloride.

Workup

  1. customA reaction

Sources & evidence

ORD record
ord-2087c756a7a1428191c0a66056837aa2
Source dataset
uspto-grants-2001_10
Patent number
US06310070B1

Reaction notes

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