HRID385271

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID20071424

1-{4-[(6-Bromohexyl)oxy]butyl}-4-nitrobenzene

C16H24BrNO3

结构：CC(C)(C)[Si](C)(C)O[C@@H](CNCCCC#Cc1ccc(NC(=O)C(F)(F)F)cc1)c1ccc(O)c2[nH]c(=O)ccc12

HCID58505275

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)[Si](C)(C)O[C@@H](CNCCCCCCOCCCCc1ccc([N+](=O)[O-])cc1)c1ccc(O)c2[nH]c(=O)ccc12

HCID58505188

未命名化合物

PROCEDURE

实验过程

The title compound was prepared in a manner analogous to that described for Intermediate 37, using Intermediate 27 in place of Intermediate 26. ES/MS calcd. for C33H50N3O6Si+ 612.4. found m/z=612.5 (M+H)+.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-36fc05ada764445f9b16e69ec7454c15
来源数据集: uspto-grants-2013_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08367829B2
来源说明: uspto-grants-2013_02

反应 SMILES

[Si:1]([O:8][C@H:9]([C:30]1[CH:39]=[CH:38][C:37]([OH:40])=[C:36]2[C:31]=1[CH:32]=[CH:33][C:34](=[O:41])[NH:35]2)[CH2:10][NH:11][CH2:12][CH2:13][CH2:14]C#CC1C=CC(NC(=O)C(F)(F)F)=CC=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].BrCCC[CH2:46][CH2:47][CH2:48][O:49][CH2:50][CH2:51][CH2:52][CH2:53][C:54]1[CH:59]=[CH:58][C:57]([N+:60]([O-:62])=[O:61])=[CH:56][CH:55]=1>>[OH:40][C:37]1[CH:38]=[CH:39][C:30]([C@H:9]([CH2:10][NH:11][CH2:12][CH2:13][CH2:14][CH2:46][CH2:47][CH2:48][O:49][CH2:50][CH2:51][CH2:52][CH2:53][C:54]2[CH:55]=[CH:56][C:57]([N+:60]([O-:62])=[O:61])=[CH:58][CH:59]=2)[O:8][Si:1]([CH3:2])([CH3:3])[C:4]([CH3:6])([CH3:7])[CH3:5])=[C:31]2[C:36]=1[NH:35][C:34](=[O:41])[CH:33]=[CH:32]2