HRID385288

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：[N-]=[N+]=NC[C@H](O)c1ccc(OCc2ccccc2)c2[nH]c(=O)ccc12

HCID58505170

未命名化合物

结构：CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1ccc(CCCCCNC[C@H](O[Si](C)(C)C(C)(C)C)c2ccc(O)c3[nH]c(=O)ccc23)cc1

HCID66989901

未命名化合物

PRODUCTS

生成物

结构：CCc1nc2c(cnn2CC)c(NC2CCOCC2)c1CNC(=O)c1ccc(CCCCCNC[C@H](O)c2ccc(O)c3[nH]c(=O)ccc23)cc1

HCID53495161

未命名化合物

PROCEDURE

实验过程

The title compound was synthesized in a manner analogous to that described for Intermediate 3, using Intermediate 44 as substrate.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-034fa12721ec431da9c98915b39a06f9
来源数据集: uspto-grants-2013_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08367829B2
来源说明: uspto-grants-2013_02

反应 SMILES

N(C[C@@H](C1C=CC(OCC2C=CC=CC=2)=C2C=1C=CC(=O)N2)O)=[N+]=[N-].[Si]([O:33][C@H:34]([C:72]1[CH:81]=[CH:80][C:79]([OH:82])=[C:78]2[C:73]=1[CH:74]=[CH:75][C:76](=[O:83])[NH:77]2)[CH2:35][NH:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][C:42]1[CH:71]=[CH:70][C:45]([C:46]([NH:48][CH2:49][C:50]2[C:51]([NH:63][CH:64]3[CH2:69][CH2:68][O:67][CH2:66][CH2:65]3)=[C:52]3[CH:60]=[N:59][N:58]([CH2:61][CH3:62])[C:53]3=[N:54][C:55]=2[CH2:56][CH3:57])=[O:47])=[CH:44][CH:43]=1)(C(C)(C)C)(C)C>>[CH2:61]([N:58]1[C:53]2=[N:54][C:55]([CH2:56][CH3:57])=[C:50]([CH2:49][NH:48][C:46](=[O:47])[C:45]3[CH:70]=[CH:71][C:42]([CH2:41][CH2:40][CH2:39][CH2:38][CH2:37][NH:36][CH2:35][C@H:34]([OH:33])[C:72]4[CH:81]=[CH:80][C:79]([OH:82])=[C:78]5[C:73]=4[CH:74]=[CH:75][C:76](=[O:83])[NH:77]5)=[CH:43][CH:44]=3)[C:51]([NH:63][CH:64]3[CH2:69][CH2:68][O:67][CH2:66][CH2:65]3)=[C:52]2[CH:60]=[N:59]1)[CH3:62]