HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,6-Dimethyl-4-pyranone → cis-2,6-dimethyloxan-4-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,6-Dimethyl-4-pyranone | HCID 13862 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | cis-2,6-dimethyloxan-4-one | HCID 10441716 | 88% |
Reaction Steps
10 g of 2,6-dimethyl-gamma-pyrone are dissolved in 200 ml of methanol and then 0.8 g of palladium-on-charcoal at 10% is added. The reaction mixture is stirred for 24 hours under 25 atmospheres of hydrogen. The medium is filtered and then the solvent is evaporated off. 8.81 g of cis-2,6-dimethyltetrahydro-pyran-4-one are recovered. Yield=88%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08372879B2 |
| Source dataset | uspto-grants-2013_02 |
| ORD ID | ord-6f65603ea42e4edab860129fe6f3e19a |
| Source note | uspto-grants-2013_02 |