huagongshe.com
HRID387402

反应详情

EQUATION

反应方程式

HRID 387402 的结构方程式

REACTANTS

反应物

2
结构：[N-]=[N+]=NCc1ccccc1
HCID12152

Benzyl azide

C7H7N3

结构：C#Cc1ccc2ccccc2c1
HCID115017

2-Ethynylnaphthalene

C12H8

PRODUCTS

生成物

1
结构：c1ccc(Cn2nncc2-c2ccc3ccccc3c2)cc1
HCID16129276

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：Cc1c(C)c(C)[c-](C)c1C.[Cl][Ru+].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1
催化剂HCID71310463

Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2)

C46H45ClP2Ru

结构：c1ccccc1
溶剂HCID241

Benzene

C6H6

PROCEDURE

实验过程

Benzyl azide (0.400 g, 3.00 mmol), 2-ethynylnaphthalene (0.503 g, 3.31 mmol), Cp*RuCl(PPh3)2 (25 mg, 0.031 mmol). Solvent, benzene; reaction temperature, 80° C.; reaction time, 4 hours; yield, 0.80 g (93%). EI-MS: m/z 285 [M+].

WORKUP

后处理

  1. customreaction temperature, 80° C.
  2. customreaction time, 4 hours
  3. customyield