HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl azide → 1-benzyl-5-(tert-butyl)-1H-1,2,3-triazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl azide | HCID 12152 | — |
| Reactant | 3,3-Dimethyl-1-butyne | HCID 13512 | — |
| Catalyst | Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2) | HCID 71310463 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 1-benzyl-5-(tert-butyl)-1H-1,2,3-triazole | HCID 16129278 | — |
Reaction Steps
Benzyl azide (0.400 g, 3.00 mmol), 3,3-dimethyl-1-butyne (0.556 ml, 4.51 mmol), Cp*RuCl(PPh3)2 (50 mg, 0.063 mmol). Solvent, benzene; reaction temperature, 80° C.; reaction time, 4 hours; yield, 0.54 g (83%). EI-MS: m/z 216 [M+1].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08372986B2 |
| Source dataset | uspto-grants-2013_02 |
| ORD ID | ord-63615a7237a043cab4726ce2838e06ff |
| Source note | uspto-grants-2013_02 |