HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl azide → 4-(1-benzyl-1H-1,2,3-triazol-5-yl)benzaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl azide | HCID 12152 | — |
| Reactant | 4-Ethynylbenzaldehyde | HCID 2771645 | — |
| Catalyst | Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2) | HCID 71310463 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 4-(1-benzyl-1H-1,2,3-triazol-5-yl)benzaldehyde | HCID 11680523 | — |
Reaction Steps
Benzyl azide (0.200 g, 1.50 mmol), 4-ethynylbenzaldehyde (0.200 g, 1.54 mmol), Cp*RuCl(PPh3)2 (25 mg, 0.031 mmol). Solvent, benzene; reaction temperature, 80° C.; reaction time, 2 hours; yield, 0.32 g (81%). EI-MS: m/z 264 [M+1].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08372986B2 |
| Source dataset | uspto-grants-2013_02 |
| ORD ID | ord-f8cb6781f79b4e22a85b531c4ad50dd2 |
| Source note | uspto-grants-2013_02 |