HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl azide → (1-benzyl-1H-1,2,3-triazol-5-yl)diphenylmethanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl azide | HCID 12152 | — |
| Reactant | Diphenylethynylcarbinol | HCID 92976 | — |
| Catalyst | Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2) | HCID 71310463 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | (1-benzyl-1H-1,2,3-triazol-5-yl)diphenylmethanol | HCID 68431884 | — |
Reaction Steps
Benzyl azide (0.200 g, 1.50 mmol), 1,1-diphenyl-2-propyn-1-ol (0.344 g, 1.65 mmol), Cp*RuCl(PPh3)2 (12 mg, 0.015 mmol). Solvent, benzene; reaction temperature, 80° C.; reaction time, 4 hours; yield, 0.39 g (75%). The reaction was performed under air. EI-MS: m/z 342 [M+1].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08372986B2 |
| Source dataset | uspto-grants-2013_02 |
| ORD ID | ord-872830791699454a8d5a26150a5d49ec |
| Source note | uspto-grants-2013_02 |