HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenylacetylene → HCID 12718991, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenylacetylene | HCID 10821 | — |
| Reactant | 1-Azidoadamantane | HCID 357114 | — |
| Catalyst | Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2) | HCID 71310463 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 12718991 | HCID 12718991 | 52% |
Reaction Steps
1-Azidoadamantane (177 mg, 1 mmol), phenylacetylene (113 mg, 1.1 mmol), Cp*RuCl(PPh3)2 (8 mg, 0.01 mmol, 1 mol %). Solvent: THF, 10 mL, 60° C., 12 hours. Product obtained as off-white powder in 52% yield (145 mg). ESI-MS: m/z 280, [M+H].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08372986B2 |
| Source dataset | uspto-grants-2013_02 |
| ORD ID | ord-cfde0d56c68f4aee919de632624f266b |
| Source note | uspto-grants-2013_02 |