HCID 54011303, compound → HCID 87489609, compound

HRID 388175Notes

Reaction equation

C(C1C(C=CC2C=CC=CC=2)=C(C=CC2C=CC=CC=2)C=CC=1)=CC1C=CC=CC=1.[CH2:31]([O:43][C:44]1[CH:45]=[C:46](/[CH:63]=[CH:64]/[C:65]2[CH:70]=[C:69](/[CH:71]=[CH:72]/[C:73]3[CH:78]=[C:77]([O:79][CH2:80][CH2:81][CH2:82][CH2:83][CH2:84][CH2:85][CH2:86][CH2:87][CH2:88][CH2:89]CC)[CH:76]=[C:75]([O:92][CH2:93][CH2:94][CH2:95][CH2:96][CH2:97][CH2:98][CH2:99][CH2:100][CH2:101][CH2:102]CC)[CH:74]=3)[CH:68]=[C:67](/[CH:105]=[CH:106]/[C:107]3[CH:112]=[C:111]([O:113][CH2:114][CH2:115][CH2:116][CH2:117][CH2:118][CH2:119][CH2:120][CH2:121][CH2:122][CH2:123]CC)[CH:110]=[C:109]([O:126][CH2:127][CH2:128][CH2:129][CH2:130][CH2:131][CH2:132][CH2:133][CH2:134][CH2:135][CH2:136]CC)[CH:108]=3)[CH:66]=2)[CH:47]=[C:48]([O:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH2:59][CH2:60]CC)[CH:49]=1)[CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40]CC>>[CH3:102][CH2:101][CH2:100][CH2:99][CH2:98][CH2:97][CH2:96][CH2:95][CH2:94][CH2:93][O:92][C:75]1[CH:74]=[C:73](/[CH:72]=[CH:71]/[C:69]2[CH:70]=[C:65](/[CH:64]=[CH:63]/[C:46]3[CH:47]=[C:48]([O:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH2:59][CH3:60])[CH:49]=[C:44]([O:43][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40])[CH:45]=3)[CH:66]=[C:67](/[CH:105]=[CH:106]/[C:107]3[CH:108]=[C:109]([O:126][CH2:127][CH2:128][CH2:129][CH2:130][CH2:131][CH2:132][CH2:133][CH2:134][CH2:135][CH3:136])[CH:110]=[C:111]([O:113][CH2:114][CH2:115][CH2:116][CH2:117][CH2:118][CH2:119][CH2:120][CH2:121][CH2:122][CH3:123])[CH:112]=3)[CH:68]=2)[CH:78]=[C:77]([O:79][CH2:80][CH2:81][CH2:82][CH2:83][CH2:84][CH2:85][CH2:86][CH2:87][CH2:88][CH3:89])[CH:76]=1

Participants

Reactant 2

HCID 54011303HCID 54011303, compound

HCID 87488382HCID 87488382, compound

Product 1

HCID 87489609HCID 87489609, compound

Procedure

The employed network molecule is derived from tristyrylbenzene, i.e. (1,3,5-tris[(E)-2-(3,5-didodecyloxyphenyl)-ethenyl]benzene). (TSB35), it has also been provided with (1,3,5-tris[(E)3,5-didodecyloxyphenyl)-ethenyl]benzene) (OC12H25 lateral arm). The latter has been solubilised in a solvent (phenyl-octane or tetradecane) at approximately 10−4 mol/L concentration. A drop of the solution has been then deposited on the freshly dived sample. The 2-D sieve thus obtained has been characterized using an STM microscope, operating directly in the liquid, whereof the tip is immersed in the drop.

Sources & evidence

ORD record: ord-9d49d80edbfe4629a0661b2070bdc3f7
Source dataset: uspto-grants-2013_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08377306B2

Reaction notes

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