HuagongsheHuagongshe Chemistry Print Report · For research reference only
m-Chloroperbenzoic acid → 5-Bromo-2-[(2R)-oxiran-2-ylmethoxy]phenyl formate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | 5-Bromo-2-[(2R)-oxiran-2-ylmethoxy]benzaldehyde | HCID 54157045 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 5-Bromo-2-[(2R)-oxiran-2-ylmethoxy]phenyl formate | HCID 54148805 | — |
Reaction Steps
Preparation according to Preparation 2 using 5-bromo-2-[(2R)-oxiran-2-ylmethoxy]benzaldehyde (6.8 g, 26 mmol), DCM (75 ml) and m-CPBA (77%, 8.9 g, 39.5 mmol). Crude yield: 7.0 g. MS m/z (rel. intensity, 70 eV) 274 (M+, 10), 273 (M+, 9), 189 (98), 188 (bp), 57 (77).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08524766B2 |
| Source dataset | uspto-grants-2013_09 |
| ORD ID | ord-41fa640187ef4f8fb80b08c6f01dcd71 |
| Source note | uspto-grants-2013_09 |