HuagongsheHuagongshe Chemistry Print Report · For research reference only
m-Chloroperbenzoic acid → 2-[(2R)-Oxiran-2-ylmethoxy]-5-[(trifluoromethyl)sulfonyl]phenyl acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | 1-{2-[(2R)-Oxiran-2-ylmethoxy]-5-[(trifluoromethyl)sulfonyl]phenyl}ethanone | HCID 86652948 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | 2-[(2R)-Oxiran-2-ylmethoxy]-5-[(trifluoromethyl)sulfonyl]phenyl acetate | HCID 86652949 | — |
Reaction Steps
Preparation according to Preparation 19 using 1-{2-[(2R)-oxiran-2-ylmethoxy]-5-[(trifluoromethyl)sulfonyl]phenyl}ethanone (1.2 g, 3.7 mmol) and m-CPBA (4.95 g, 22.5 mmol) in CHCl3 (50 ml). Crude yield 1.0 g. MS m/z (rel. intensity, 70 eV) 298 (34), 229 (77), 165 (bp), 107 (39), 79 (30).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08524766B2 |
| Source dataset | uspto-grants-2013_09 |
| ORD ID | ord-6905ee7f6693420b9421b05e3dd2f47d |
| Source note | uspto-grants-2013_09 |