HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 392011Generated: October 25, 2026
Dicyclopentadiene → 8-(2,2,2-Trifluoro-1-trifluoromethyl-1-hydroxyethyl)tetracyclo[4.4.0.12,5.17,10]dodec-3-ene
https://huagongshe.com/reaction/392011
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Dicyclopentadiene | HCID 6492 | — |
| Reactant | 4-Penten-2-ol, 1,1,1-trifluoro-2-(trifluoromethyl)- | HCID 328870 | — |
| Product | 8-(2,2,2-Trifluoro-1-trifluoromethyl-1-hydroxyethyl)tetracyclo[4.4.0.12,5.17,10]dodec-3-ene | HCID 20617087 | 22.2% |
Reaction Steps
A 500 ml autoclave was charged with 230 g of 1,1-bis(trifluoromethyl)-3-butenol, 73 g of dicyclopentadiene, and 0.15 g of 2,6-di-t-butylparacresol, and the mixture was heated at 190° C. for 12 hours. The reaction solution was cooled to room temperature and purified by distillation to obtain 40 g of 8-(2,2,2-trifluoro-1-trifluoromethyl-1-hydroxyethyl)tetracyclo[4.4.0.12,5.17,10]dodec-3-ene of the following formula (13).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US06800414B2 |
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| Source dataset | uspto-grants-2004_10 |
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| ORD ID | ord-c5a8c281d9034da7adddb676a06667da |
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| Source note | uspto-grants-2004_10 |
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