HRID392944

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID24386

Thionyl chloride

Cl2OS

结构：CCO[Si](OCC)(c1c(F)c(F)c(F)c(F)c1F)c1c(F)c(F)c(F)c(F)c1F

HCID11102434

未命名化合物

HCID21584435

未命名化合物

PRODUCTS

生成物

结构：Fc1c(F)c(F)c([Si](Cl)(Cl)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F

HCID11112867

di(pentafluorophenyl)dichlorosilane

C12Cl2F10Si

PROCEDURE

实验过程

180.93 g (0.400 mol) di(pentafluorophenyl)diethoxysilane, 146 mL (2.00 mol, 237.9 g) thionylchloride and 4.92 g (0.0426 mol) pyridinium hydrochloride are refluxed and stirred for 16 h. Excess of SOCl2 is evaporated and di(pentafluorophenyl)dichlorosilane isolated by vacuum-distillation.

WORKUP

后处理

customExcess of SOCl2 is evaporated