Allyl bromide → HCID 131724626, compound

Participants

Reaction Steps

2.400 g (11.42 mmol) of dimethyl 5-hydroxyisophthalic acid, 1.4 g (11.6 mmol) of 3-bromopropene and 1.6 g (11.6 mmol) of potassium carbonate were dispersed in 40 ml of acetone and stirred for 15 hours at reflux temperature. The mixture was cooled to room temperature and filtered off insoluble salts after the addition of 150 ml of diethylether. The filtrate was concentrated and purified through the silicagelcolumn chromatography (developing solvent: diethylether/hexane=½), 2.612 g of dimethyl 5-allyloxyisophthalic acid in water-white solid powder was obtained (yield: 94.1%).

Provenance & Evidence