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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 393973Generated: October 25, 2026

1,6-Hexanediol → 5,7-di-tert-butyl-3-(4-n-octyloxycarbonylphenyl)-3H-benzofuran-2-one

https://huagongshe.com/reaction/393973

Reaction equation

Participants

RoleNameHCIDCharge
Reactant1,6-HexanediolHCID 12374—
Reactant1,12-DodecanediolHCID 79758—
Reactant5,7-di-tert-butyl-3-(4-methoxycarbonylphenyl)-3H-benzofuran-2-oneHCID 12162160—
Product5,7-di-tert-butyl-3-(4-n-octyloxycarbonylphenyl)-3H-benzofuran-2-oneHCID 22648338—

Reaction Steps

Compounds (111), (112), (113), (114), (115), (116) and (117) (Table 1) are obtained in analogy to Example 5 using 1-dodecanol, 1-octadecanol, 1-nonadecanol, 1-docosanol, 2-ethylhexanol, 1,6-hexanediol and 1,12-dodecanediol instead of 1-octanol. For the preparation of compounds (116) and (117) only half of an equivalent of 1,6-hexanediol and 1,12-dodecanediol in respect to the compound (109) was used.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06809208B2
Source datasetuspto-grants-2004_10
ORD IDord-4c4698c17a3644e8b1679f03c35a3398
Source noteuspto-grants-2004_10