HCID 11014352, compound → HCID 10948865, compound

HRID 394904Notes

Reaction equation

HRID 394904 reaction equation
[CH3:1][P@@:2]([C:17]([CH3:24])([CH3:23])[CH2:18][C:19]([CH3:22])([CH3:21])[CH3:20])([CH2:4][CH2:5][P@@:6]([CH3:16])([C:8]([CH3:15])([CH3:14])[CH2:9][C:10]([CH3:13])([CH3:12])[CH3:11])=[O:7])=[O:3]>C(Cl)(Cl)Cl>[CH3:16][P:6]([C:8]([CH3:15])([CH3:14])[CH2:9][C:10]([CH3:13])([CH3:12])[CH3:11])([CH2:5][CH2:4][P:2]([CH3:1])([C:17]([CH3:23])([CH3:24])[CH2:18][C:19]([CH3:20])([CH3:21])[CH3:22])=[O:3])=[O:7]

Participants

3

Reactant 1

HCID 11014352HCID 11014352, compound

Product 1

HCID 10948865HCID 10948865, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

The resultant product was found to be (−)-(S, S)-1,2-bis-[methyl(1,1,3,3-tetramethylbutyl)phosphinoyl]ethane having an optical rotation of [α] 25D=−2.85 (C 1.05, CHCl3). The results of this compound analyzed by NMR and other means are shown below.

Workup

  1. customThe results of this compound

Sources & evidence

ORD record
ord-6ab30f3544924f4485fec39f443455ae
Source dataset
uspto-grants-2003_08
Patent number
US06603032B1

Reaction notes

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