HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-[5-(Benzyloxy)-2-nitrophenyl]-3-methyl-2-buten-1-ol → 1-[5-(Benzyloxy)-2-nitrophenyl]-3-methyl-2-buten-1-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-[5-(Benzyloxy)-2-nitrophenyl]-3-methyl-2-buten-1-ol | HCID 23003056 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 1-[5-(Benzyloxy)-2-nitrophenyl]-3-methyl-2-buten-1-one | HCID 23003080 | 81% |
Reaction Steps
In an analogous manner to the procedure of Example VI, 1.70 g (5.43 mmol) of 1-[5-(benzyloxy)-2-nitrophenyl]-3-methyl-2-buten-1-ol are reacted with 4.25 g (48.83 mmol) of manganese dioxide in 30 ml of dichloromethane to give 1.37 g (81%) of 1-[5-(benzyloxy)-2-nitrophenyl]-3-methyl-2-buten-1-one.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06608049B2 |
| Source dataset | uspto-grants-2003_08 |
| ORD ID | ord-ca38cbf5acbd48478ae5daaecad29d56 |
| Source note | uspto-grants-2003_08 |