HuagongsheHuagongshe Chemistry Print Report · For research reference only
Lactic Acid → (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Lactic Acid | HCID 612 | — |
| Reactant | Glyceric acid | HCID 752 | — |
| Reactant | Glycolic Acid | HCID 757 | — |
| Reactant | Carbonic Acid | HCID 767 | — |
| Reactant | Oxalic Acid | HCID 971 | — |
| Reactant | Erythronic acid | HCID 2781043 | — |
| Product | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | 25% |
Reaction Steps
This type of alkaline oxidative degradation, which is 25 effective both on hemiacetal functions and on ketone functions, also entails the formation of by-products such as, in particular, carbonic acid, oxalic acid, glyceric acid, glycolic acid, lactic acid, erythronic acid and, of course, fornic acid, which are obtained in a molar yield of about 25% from glucose when the alkalinity conditions are such that they allow a 75% yield of arabinonate. Formic acid is always produced in yields close to 100% of the stoichiometry.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05817780 |
| Source dataset | uspto-grants-1998_10 |
| ORD ID | ord-7c204958a2f44b7ea5aa2ea832301073 |
| Source note | uspto-grants-1998_10 |