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HRID399283

反应详情

EQUATION

反应方程式

HRID 399283 的结构方程式

REACTANTS

反应物

4
结构：COC(=O)Cl
HCID6586

Methyl chlorocarbonate

C2H3ClO2

结构：CCOC(=O)C#Cc1ccc2c(c1)C(C)(C)CCC2(C)C
HCID11000580

未命名化合物

2 次

结构：C#Cc1cc2c(cc1C)C(C)(C)CCC2(C)C
HCID11806387

未命名化合物

结构：[Li]CCCC
HCID178418339

未命名化合物

PRODUCTS

生成物

1
结构：CCOC(=O)C#Cc1cc2c(cc1C)C(C)(C)CCC2(C)C
HCID18357952

未命名化合物

PROCEDURE

实验过程

Employing the same general procedure as used for the preparation of ethyl 3-[5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphth-2-yl]propiolate (Compound A), but instead using 1.9 g of (3-methyl-5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphth-2-yl)ethyne, 940 mgs (10 mmols) of methylchloroformate and 8.8 mmols of n-butyllithium the title compound was obtained as an oil.