Acetyl chloride → HCID 85766638, compound

Participants

Reaction Steps

94.8 g (0.5 mol) of tin(II) chloride and 50 g (0.5 mol) of acetylacetone were placed in a reactor at room temperature. 39.3 g (0.5 mol) of acetyl chloride were metered in over 45 min, the temperature rising to 45° C. The highly viscous, partially crystalline reaction mixture was stirred for 2 h, 50 ml of n-pentane were added and the solid formed was separated off. After washing with 100 ml of n-pentane and drying, 140 g (92% of theory) of 1-methylbut-1-en-3-onyltin trichloride were isolated.

Provenance & Evidence