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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 399305Generated: October 31, 2026

Aniline → 2-Methyl-N-phenylaniline

https://huagongshe.com/reaction/399305

Reaction equation

Participants

RoleNameHCIDCharge
ReactantAnilineHCID 6115—
Reactanto-Tolyl TrifluoromethanesulfonateHCID 572025—
Product2-Methyl-N-phenylanilineHCID 1098694695%

Reaction Steps

The general procedure B using 51.7 mg (0.215 mmol) of o-tolyltriflate and 29.4 μl (0.323 mmol) of aniline gave 95% yield of N-(2-methylphenyl)aniline after sublimation (130° C., 0.1 torr).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05817877
Source datasetuspto-grants-1998_10
ORD IDord-b9f1d7ea746c4da38b47288f08726e2e
Source noteuspto-grants-1998_10