HRID399313

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：C[Si](C)(C)OC(c1cc(Br)c(C(O[Si](C)(C)C)C(F)(F)C(F)(F)C(F)(F)F)[nH]1)C(F)(F)C(F)(F)C(F)(F)F

HCID21848613

未命名化合物

HCID178506397

未命名化合物

PRODUCTS

生成物

结构：C[Si](C)(C)OC(c1cc(C(F)(F)F)c(C(O[Si](C)(C)C)C(F)(F)C(F)(F)C(F)(F)F)[nH]1)C(F)(F)C(F)(F)C(F)(F)F

HCID21848611

未命名化合物

PROCEDURE

实验过程

Trifluoromethylzinc chloride is reacted with 3-bromo-2,5-bis(2,2,3,3,4,4,4-heptafluoro-1-trimethylsilyloxybutyl)pyrrole utilizing reaction and purification conditions described in Example 22.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-575141ba5b6149ae835c2a0450a47180
来源数据集: uspto-grants-1998_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05817830
来源说明: uspto-grants-1998_10

反应 SMILES

[Cl-].[F:2][C:3]([Zn+])([F:5])[F:4].Br[C:8]1[CH:12]=[C:11]([CH:13]([O:24][Si:25]([CH3:28])([CH3:27])[CH3:26])[C:14]([F:23])([F:22])[C:15]([F:21])([F:20])[C:16]([F:19])([F:18])[F:17])[NH:10][C:9]=1[CH:29]([O:40][Si:41]([CH3:44])([CH3:43])[CH3:42])[C:30]([F:39])([F:38])[C:31]([F:37])([F:36])[C:32]([F:35])([F:34])[F:33]>>[F:39][C:30]([F:38])([C:31]([F:36])([F:37])[C:32]([F:33])([F:34])[F:35])[CH:29]([C:9]1[NH:10][C:11]([CH:13]([O:24][Si:25]([CH3:28])([CH3:27])[CH3:26])[C:14]([F:22])([F:23])[C:15]([F:20])([F:21])[C:16]([F:17])([F:18])[F:19])=[CH:12][C:8]=1[C:3]([F:5])([F:4])[F:2])[O:40][Si:41]([CH3:42])([CH3:43])[CH3:44]