Cesium carbonate → HCID 63530802, compound

HRID 402789Notes

Reaction equation

[Br:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[C:4]([CH3:9])[CH:3]=1.C(=O)([O-])[O-].[Cs+].[Cs+].Br[CH2:17][CH:18]=[C:19]([CH3:21])[CH3:20]>>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([O:8][CH2:17][CH:18]=[C:19]([CH3:21])[CH3:20])=[C:4]([CH3:9])[CH:3]=1

Participants

Reactant 3

HCID 10796Cesium carbonate

HCID 168964-Bromo-2-methylphenol

HCID 700922-Butene, 1-bromo-3-methyl-

Product 1

HCID 63530802HCID 63530802, compound

Procedure

Using essentially the same procedure as Example 5-20, Step 1, 4-bromo-2-methylphenol (1.00 g, 5.35 mmol), cesium carbonate (3.48 g, 10.7 mmol) and 4-bromo-2-methyl-2-butene (0.75 mL, 6.42 mmol) afforded the desired product as a pale-yellow oil.

Sources & evidence

ORD record: ord-b93ef6b2835c40538f4df431d2030005
Source dataset: uspto-grants-2014_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08742110B2

Reaction notes

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