Azobisisobutyronitrile → HCID 131731622, compound

Participants

Reaction Conditions

Reaction Steps

In a mixed solvent of 75 g of methanol and 25 g of ion-exchanged water were dissolved 18.40 g (68.32 mmol) of 11-methacrylamidoundecanoic acid (MAU), 1.60 g (7.59 mmol) of 2-methacryloxyethyl phosphoric acid (Phosmer-M: Uni-Chemical Co.), 0.30 g (7.59 mmol) of sodium hydroxide, and 0.31 g (1.89 mmol) of azobisisobutyronitrile (Nacalai Tesque, Inc.). The solution was deaerated by bubbling nitrogen for 60 minutes. The container was covered with a septum, and the polymerization was conducted by heating at 60° C. for 20 hours. After the completion of the polymerization reaction, a gelatinous product was obtained. This product was dried under reduced pressure, and 6.0 g of the dried material was added to 200 g of methanol. After sufficient stirring, insoluble material was removed by filtration. The obtained solution was dropwise added into a large excess of ethyl acetate, and the resulting precipitate was collected by filtration under suction. After drying under reduced pressure, 2.01 g of random MAU/2-methacryloxyethyl phosphoric acid copolymer (90/10) was obtained. The weight average molecular weight was 190000.

Provenance & Evidence