Iron(2+) tetrafluoroborate--water (1/2/6) → Iron(II) tetrafluoroborate

HRID 411120Notes

Reaction equation

HRID 411120 reaction equation
O.O.O.O.O.O.[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17]>ClCCl>[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17]

Participants

3

Reactant 1

HCID 15762351Iron(2+) tetrafluoroborate--water (1/2/6)

Product 1

HCID 11736352Iron(II) tetrafluoroborate

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

To a suspension of iron(II) bis(tetrafluoroborate) hexahydrate (4.9 mg; 15 μmol) in dichloromethane was added a solution of h17 (5.0 mg; 14 μmol) in a few milliliters of dichloromethane. The solution turned from light yellow to dark orange with time within 18 hours. The solution was used as is in further polymerization study.

Workup

  1. customwithin 18 hours

Sources & evidence

ORD record
ord-1cf332f0753f430f9b184927c597e821
Source dataset
uspto-grants-2003_05
Patent number
US06559091B1

Reaction notes

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