Ethylene → Iron(II) tetrafluoroborate

HRID 411121Notes

Reaction equation

HRID 411121 reaction equation
O.O.O.O.O.O.[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17].C=C>ClCCl>[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17]

Participants

4

Reactant 2

HCID 6325EthyleneHCID 15762351Iron(2+) tetrafluoroborate--water (1/2/6)

Product 1

HCID 11736352Iron(II) tetrafluoroborate

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

A solution of h25 (5.1 mg; 8.9 μmol) in about 2 mL dichloromethane was added to a suspension of iron bis(tetrafluoroborate) hexahydrate (3.0 mg; 8.9 μmol) in dichloromethane. The mixture was stirred at room temperature for about 18 hours before being used in the polymerization of ethylene.

Sources & evidence

ORD record
ord-61de968a3f224444908babe29686ce50
Source dataset
uspto-grants-2003_05
Patent number
US06559091B1

Reaction notes

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