methyl (1R,3S,4S)-3-methoxy-4-(nitrooxy)cyclopentanecarboxylate → (1RS,3RS,4SR)-3-methoxy-4-(nitrooxy)cyclopentanecarboxylic acid

Participants

Reaction Steps

The title compound was prepared by following step D for example 1, except that the reagent (+)-methyl (1R,3S,4S)-3-methoxy-4-(nitrooxy)cyclopentanecarboxylate was replaced by methyl (1RS,3RS,4RS)-3-methoxy-4-(nitrooxy)cyclopentanecarboxylate. 1H NMR (500 MHz, CDCl3) δ 2.10-2.19 (m, 3H), 2.57-2.65 (m, 1H), 3.14 (m, 1H), 3.41 (s, 3H), 3.90 (m, 1H), 5.23-5.27 (m, 1H).

Provenance & Evidence