Fluorimide → HCID 18539305, compound

HRID 412732Notes

Reaction equation

[F:1][N:2]([F:26])C1(N(F)F)CN([N+]([O-])=O)CC([N+]([O-])=O)([N+]([O-])=O)CN([N+]([O-])=O)C1.[N+:27]([C:30]1([N+:63]([O-:65])=[O:64])[CH2:37][N:36]([S:38]([C:41]2[CH:46]=[CH:45][CH:44]=[CH:43][C:42]=2[N+:47]([O-:49])=[O:48])(=[O:40])=[O:39])[CH2:35][C:34](=O)[CH2:33][N:32]([S:51]([C:54]2[CH:59]=[CH:58][CH:57]=[CH:56][C:55]=2[N+:60]([O-:62])=[O:61])(=[O:53])=[O:52])[CH2:31]1)([O-:29])=[O:28].[NH:66]([F:68])[F:67]>>[F:1][N:2]([F:26])[C:34]1([N:66]([F:68])[F:67])[CH2:35][N:36]([S:38]([C:41]2[CH:46]=[CH:45][CH:44]=[CH:43][C:42]=2[N+:47]([O-:49])=[O:48])(=[O:40])=[O:39])[CH2:37][C:30]([N+:63]([O-:65])=[O:64])([N+:27]([O-:29])=[O:28])[CH2:31][N:32]([S:51]([C:54]2[CH:59]=[CH:58][CH:57]=[CH:56][C:55]=2[N+:60]([O-:62])=[O:61])(=[O:53])=[O:52])[CH2:33]1

Participants

Reactant 3

HCID 25242Fluorimide

HCID 11452243HCID 11452243, compound

HCID 18539306HCID 18539306, compound

Product 1

HCID 18539305HCID 18539305, compound

Procedure

In a preferred embodiment of the present invention, the method of making a 3,3-bis(difluoramino)octahydro -1,5,7,7-tetranitro-1,5-diazocine comprises reacting a hexahydro-7,7-dinitro-1,5-bis(nitrobenzenesulfonyl)-1,5-diazocin-3(2H)-one with a difluoramine source to produce a 3,3-bis(difluoramino)octahydro-7,7-dinitro-1,5-bis(nitrobenzenesulfonyl)-1,5-diazocine and reacting said 3,3-bis(difluoramino)octahydro-7,7-dinitro-1,5-bis(nitrobenzenesulfonyl)-1,5-diazocine with a highly reactive nitrating reagent in the presence of a strong Lewis acid, such as antimony pentafluoride, boron triflate or boron fluorosulfonate.

Sources & evidence

ORD record: ord-e6cdf07e45694e349d4793efc7c6b041
Source dataset: uspto-grants-2003_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06562985B2

Reaction notes

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