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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 413557Generated: October 28, 2026

Peracetic Acid → 4a,7-Methano-4aH-naphth[1,8a-b]oxirene, octahydro-4,4,8,8-tetramethyl-

https://huagongshe.com/reaction/413557

Reaction equation

Participants

RoleNameHCIDCharge
ReactantPeracetic AcidHCID 6585—
Reactant2H-2,4a-Methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-, (2S)-HCID 102562—
Product4a,7-Methano-4aH-naphth[1,8a-b]oxirene, octahydro-4,4,8,8-tetramethyl-HCID 107035—

Reaction Steps

In the first stage, isolongifolene (1) can be reacted in a known manner, for example with peracetic acid, to give isolongifolene oxide (2) (Tetrahedron Lett. 1964, 8, 417; J. Org. Chem. 1970, 35, 1172).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06566562B2
Source datasetuspto-grants-2003_05
ORD IDord-23c61cac9e6d4f11852bd95e4e78c379
Source noteuspto-grants-2003_05