HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acrolein → 6,6-dimethylhept-1-en-4-yn-3-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acrolein | HCID 7847 | — |
| Reactant | 3,3-Dimethyl-1-butyne | HCID 13512 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Product | 6,6-dimethylhept-1-en-4-yn-3-ol | HCID 10975561 | — |
Reaction Steps
Reacting t-butylacetylene at −40° C. or less with butyllithium, cooling the reaction mixture at −40° C. or less with acrolein further aging the reaction mixture at −50° C. for 30 minutes to give 6,6-dimethylhept-1-en-4-yn-3-ol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06570044B2 |
| Source dataset | uspto-grants-2003_05 |
| ORD ID | ord-b13b8cd3b2b34eedb67cde019d386a07 |
| Source note | uspto-grants-2003_05 |