HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → 3-Chloroanthracen-9(10h)-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | 2-Chloroanthraquinone | HCID 8553 | — |
| Reactant | Tin atom | HCID 5352426 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 3-Chloroanthracen-9(10h)-one | HCID 78601 | — |
| Product | 2-Chloroanthrone | HCID 13013513 | — |
Reaction Steps
Tin powder (100 g) and 2-chloroanthraquinone (70 g) were refluxed in acetic acid (500 ml) while concentrated hydrochloric acid (130 ml) was added over a period of 3 hours. The solution was cooled and the product was separated by filtration, and then chromatographed on silica gel, eluting with benzene:ether, so as to afford 2-chloroanthrone and 3-chloroanthrone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04792551 |
| Source dataset | uspto-grants-1988_12 |
| ORD ID | ord-69046feb53fc41adb7568e4b0908623c |
| Source note | uspto-grants-1988_12 |