HCID 13092056, compound → HCID 53947757, compound

HRID 414652Notes

Reaction equation

[Cl:1][C:2]1[CH:18]=[C:17]([C:19]([F:22])([F:21])[F:20])[CH:16]=[CH:15][C:3]=1[O:4][C:5]1[CH:6]=[CH:7][C:8]([N+:12]([O-:14])=[O:13])=[C:9]([O-:11])[CH:10]=1.[K+].Br[CH:25]([CH3:38])[C:26]([O:28][CH2:29][P:30](=[O:37])([O:34][CH2:35][CH3:36])[O:31][CH2:32][CH3:33])=[O:27]>>[Cl:1][C:2]1[CH:18]=[C:17]([C:19]([F:21])([F:20])[F:22])[CH:16]=[CH:15][C:3]=1[O:4][C:5]1[CH:6]=[CH:7][C:8]([N+:12]([O-:14])=[O:13])=[C:9]([CH:10]=1)[O:11][CH:25]([CH3:38])[C:26]([O:28][CH2:29][P:30](=[O:37])([O:34][CH2:35][CH3:36])[O:31][CH2:32][CH3:33])=[O:27]

Participants

Reactant 2

HCID 13092056HCID 13092056, compound

HCID 13535036HCID 13535036, compound

Product 1

HCID 53947757HCID 53947757, compound

Procedure

by using potassium 5-(o-chloro-p-trifluoromethyl-phenoxy)-2-nitrophenolate and diethyl (2-bromopropionyloxy)-methylphosphonate there is obtained diethyl [2-[5-(o-chloro-p-trifluoromethyl-phenoxy)-2-nitrophenoxy]-propionyloxy]methylphosphonate, 1H-NMR (CDCl3 ; 400 MHz) 7.93 ppm (d, 1H), 7.79 ppm (d, 1H), 7.58 ppm (q, 1H), 7.21 ppm (d, 1H), 6.63 ppm (d, 1H), 6.49 ppm (q, 1H), 4.89 ppm (q, 1H), 4.45 ppm (m, 2H), 4.14 ppm (m, 4H), 1.74 ppm (d, 3H), 1.32 ppm (tt, 6H).

Sources & evidence

ORD record: ord-0dec3094b0c0494f82f9e4fe6abb131f
Source dataset: uspto-grants-1988_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04792616

Reaction notes

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