HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 86621462, compound → HCID 86621461, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 86621462 | HCID 86621462 | — |
| Reactant | HCID 178418634 | HCID 178418634 | — |
| Product | HCID 86621461 | HCID 86621461 | — |
Reaction Steps
Thioacetic acid S-[2-(9H-fluoren-9-ylmethoxycarbonylamino)-2-methyl-propyl]ester was prepared by an analogous procedure as described in example 26 ii) starting from 6.19 g (15.9 mmol) methanesulfonic acid 2-(9H-fluoren-9-ylmethoxycarbonylamino)-2-methyl-propyl ester and 2.1 ml (1.8 equiv.) thioacetic acid. Purification by flash chromatography on silica gel (eluent: CH2Cl2) gave pure thioacetic acid S-[2-(9H-fluoren-9-ylmethoxycarbonylamino)-2-methyl-propyl]ester as yellow oil. Yield: 1.87 g MS (ES+): m/e=370.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08088925B2 |
| Source dataset | uspto-grants-2012_01 |
| ORD ID | ord-cf692c69e43d46639e770f4d08adbc8d |
| Source note | uspto-grants-2012_01 |