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HRID41659

反应详情

EQUATION

反应方程式

HRID 41659 的结构方程式

REACTANTS

反应物

2
结构：C[Si](C)(C)N(c1ccccc1)C12CC3CC(CC(C3)C1)C2
HCID66604537

未命名化合物

结构：CC(C)(C)N(C=[N+](c1ccccc1)C(C)(C)C)c1ccccc1.[Cl-]
HCID66607390

未命名化合物

PRODUCTS

生成物

1
结构：C(N(c1ccccc1)C12CC3CC(CC(C3)C1)C2)=[N+](c1ccccc1)C12CC3CC(CC(C3)C1)C2.[Cl-]
HCID66607202

未命名化合物

收率 71.5%

PROCEDURE

实验过程

With the same method used in the synthesis of 4a except for adding 3b (2 equiv), 4b (71.5%) was obtained as a white solid. 1H NMR (300 MHz, CD2Cl2) δ=8.71 (s, 1H), 7.24-6.90 (m, 6H), 6.78 (d, J=7.4 Hz, 4H), 2.21 (br. s, 6H), 2.07-1.99 (m, 12H), 1.66 (br. s, 12H); 13C NMR (75 MHz, CD2Cl2) δ 152.7, 135.0, 130.3, 129.0, 128.9, 66.6, 41.8, 35.4, 30.5. HRMS-DART (m/z): [M]+ calcd for C33H41ClN2, 465.3264. found, 465.3249.