HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → 4-[2-(9,9-Dibutyl-7-ethynyl-9H-fluoren-2-yl)ethynyl]-N,N-dihexylbenzenamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | [9,9-Dibutyl-7-[2-[4-(dihexylamino)phenyl]ethynyl]-9H-fluorene-2-yl]-2-methyl-3-butyn-2-ol | HCID 86646643 | — |
| Solvent | Toluene isopropyl alcohol | HCID 21881414 | — |
| Product | 4-[2-(9,9-Dibutyl-7-ethynyl-9H-fluoren-2-yl)ethynyl]-N,N-dihexylbenzenamine | HCID 86646642 | 87% |
Reaction Steps
Potash powder (0.07 g) is added to a solution of 5a (0.798 g, 1.24 mmol) in 8.75 mL of toluene/i-PrOH (6/1). The mixture is heated in a reverse-flow boiler for 1 h. After cooling, the potash is filtered and the solvents are evaporated. The raw product is purified by silica gel column chromatography (heptane/CH2Cl2 90:10) to yield 0.632 g (87%) of 5b.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08535643B2 |
| Source dataset | uspto-grants-2013_09 |
| ORD ID | ord-03ed10cb8a41497eab0f16a59da04230 |
| Source note | uspto-grants-2013_09 |